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Power Professional

Industry : Power Functional Area : R&D
Activity:  5 comments  173 views  last activity : 04 15 2012 23:15:25 +0000
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In today's news, I came across this article that scientists at Sandia National Labs who were seeking a means to create cheap and abundant hydrogen to power a hydrogen economy, realized they could use the same technology to "reverse-combust" CO2 back into fuel. They still have to improve the efficiency of the system, but they recently demonstrated a working prototype of their "Sunshine to Petrol" converting waste CO2 to carbon monoxide, and then syngas, consuming nothing but solar energy.

The device, boasting the simple title Counter-Rotating-Ring Receiver Reactor Recuperator (CR5) sets off a thermo-chemical reaction by exposing an iron-rich composite to concentrated solar heat. The composite sheds an oxygen molecule when heated and gets one back as it cools, and therein lies the fuel. The cylindrical metal CR5 is divided into hot and cold chambers. Solar energy heats the hot chamber to a scorching 2,700 degrees, which forces the iron oxide composite to lose oxygen atoms. The composite is then thrust into the cool chamber, which is filled with carbon dioxide. As it cools, the iron oxide snatches back its lost oxygen atoms, leaving behind carbon monoxide.

The same process can also produce raw hydrogen by pumping water rather than CO2 into the cool chamber. Hydrogen and carbon monoxide can then be blended into syngas, a replacement for current hydrocarbon-based combustibles like gasoline, diesel and jet fuel. While it's not a total solution for carbon emissions -- syngas, burns right back into CO2 -- it is an alternative to sequestering carbon underground. CO2 recycling could be used to trap waste carbon from factories and power plants and return that energy to productive use, rather than releasing it into the air, where it can cause problems. A market-ready CR5 device is still more than a decade away, but the idea of taking waste carbon and turning it directly back into fuel using nothing but abundant solar rays is tantalizing.

 
3 comments on "New Reactor Uses Sunlight to Turn Water and Carbon Dioxide Into Fuel"
  Commented by  Anup Kundu, QA/QC Manager, Accenture    | 11 24 2009 07:27:37 +0000
This is another one of those pre-emptive articles where people have something that kinda works, but doesn't really yet.
It would take the same amount of energy to create this fuel (probably more depending on efficiency) then you would get from burning it again so there's no real energy crisis solution.
  Commented by  Govind Patil, Project Manager, IBM    | 11 24 2009 07:24:24 +0000
Really this is just using solar as a heat source - mass produced nuclear power is a much cheaper heat source so for a large scale operation. As a small scale unit in remote and off the grid places, it'd be a great source of fuel. The most important thing is how efficient is this system which the article does not say it. If the overall efficiency will be lower than solar panel, solar-thermal etc. systems then it cannot be successful.
  Commented by  Harvinder Bina, QA/QC Manager, TCS    | 11 24 2009 07:22:48 +0000
This is very interesting. If we were to capture the CO2 that is let off after the syngas is burned, we could make a cycle that would continue to use the same fuel over and over again, thus cutting down our emissions tremendously. I hope this truly works and lives up to it's potential. This might be a means of thermal energy storage locked into a hydrocarbon that would finally exceed the energy density of hydrogen. This has a few applications on Earth, but MANY applications for space colonization. Coupled with fuel-cell and Solar technology we could virtually solve the power problem with running a lunar colony, or gods forbid, a Martian colony.
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